Diffusion of plasticizers in rubbery poly(vinyl chloride

Plasticiser loss from plastic or rubber products through

Classification:Chemical Auxiliary Agent
Other Names:Plasticizer
Purity:99.5% min.
Type:Oil drilling
Usage:Coating Auxiliary Agents, Leather Auxiliary Agents, Plastic Auxiliary Agents, Rubber Auxiliary Agents
MOQ:200kgs
Package:200kgs/battle
Shape:Powder
Place of Origin::China
Item:T/T,L/C

Schematic of a diffusion-controlled and b evaporation-controlled plasticiser loss from polymers to a gas phase, and c image of a nitrile butadiene rubber (NBR) sample aged at

Self-diffusion of commercial plasticizers in PVC was studied by NMR at temperatures between 75 and 175°C and at concentrations c from 10 to 60 wt % plasticizer. Diffusion of the neat

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Thermomechanical Properties of Nontoxic

Classification:Chemical Auxiliary Agent, Chemical Auxiliary Agent
Other Names:Plasticizer
Purity:99.5%min
Type:Oil drilling
Usage:Coating Auxiliary Agents, Leather Auxiliary Agents, Petroleum Additives, Plastic Auxiliary Agents, Rubber Auxiliary Agents, Surfactants, Textile Auxiliary Agents
MOQ:25kg/bag
Package:200kg/drum
Application:PVC Plasticizer

Environmental and toxicity concerns dictate replacement of di(2-ethylhexyl) phthalate (DEHP) plasticizer used to impart flexibility and thermal stability to polyvinyl chloride (PVC). Potential alternatives to DEHP in PVC

1. Introduction. Polyvinyl chloride (PVC) plays a key role in the production of a large variety of products including building materials, furniture, toys, medical devices, electrical

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Plasticiser loss from plastic or rubber products

Classification:Chemical Auxiliary Agent, Chemical Auxiliary Agent
Other Names:Plasticizer
Purity:99.5
Type:Plastizer
Usage:Leather Auxiliary Agents, Plastic Auxiliary Agents, Plasticizer
MOQ:25kg/bag
Package:200kg/drum
Place of Origin:Henan, China

This paper addresses the kinetics and predictions of plasticiser migration from polymers to a surrounding gas phase, an important issue for plastic and rubber products exposed to high service

Thus, the effectiveness of the plasticizer in lowering the glass transition temperature will be expected to be related to the self-diffusion coefficient of the plasticizer molecules. The

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Enhanced migration of plasticizers from polyvinyl chloride

Classification:Chemical Auxiliary Agent
Other Names:Plasticizer
Purity:99.0%Min
Type:Adsorbent, plasticizer
Usage:Plastic Auxiliary Agents, Rubber Auxiliary Agents
MOQ:1000KG
Package:25kg/drum
Shape:Powder
Application:PVC Plasticizer

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1 INTRODUCTION. Poly(vinyl chloride) (PVC) is the common plastics in use worldwide because of its low cost, compoundability, superior mechanical and physical

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Bio-Based Plasticizers for Polyvinylchloride (PVC)

Classification:Chemical Auxiliary Agent, Chemical Auxiliary Agent
Other Names:Plasticizer
Purity:99.5
Type:Oil drilling
Usage:Coating Auxiliary Agents, Leather Auxiliary Agents, Plastic Auxiliary Agents, Rubber Auxiliary Agents, Plastic Auxiliary Agents, Rubber Auxiliary Agents
MOQ:200kgs
Package:200kgs/battle
Shape:Powder

Polyvinylchloride (PVC) is a thermoplastic polymer showing low cost and excellent general properties [].PVC is one of the six most commonly used plastics (PE, PP, PS, PVC,

Dec 1, 1994Plasticizer migration studies dealing with poly(vinyl chloride) (PVC) sheets and liquid surrounding media revealed two parallel phenomena, migration of plasticizer

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What is the diffusion coefficient of a plasticizer in PVC?
In contrast, our study examines directly the diffusion of a plasticizer within the PVC. The Kim et al. (60) experimental study found the diffusion coefficient of PVC plasticized with 40 wt % DEHP at 40 °C to be 4.77 × 10 –10 or 5.75 × 10 –10 m 2 /s depending on the solvent in which the PVC was submerged.
What are alternative plasticizers for polyvinyl chloride (PVC)?
Environmental and toxicity concerns dictate replacement of di (2-ethylhexyl) phthalate (DEHP) plasticizer used to impart flexibility and thermal stability to polyvinyl chloride (PVC). Potential alternatives to DEHP in PVC include diheptyl succinate (DHS), diethyl adipate (DEA), 1,4-butanediol dibenzoate (1,4-BDB), and dibutyl sebacate (DBS).
Is there a bio-based plasticizer for poly (vinyl chloride)?
Feng G, Hu L, Ma Y, Jia P, Hu Y, Zhang M, Liu C, Zhou Y (2018) An efficient bio-based plasticizer for poly (vinyl chloride) from waste cooking oil and citric acid: synthesis and evaluation in PVC films.
How does plasticizer content affect the diffusivity of polymers?
With increase in the plasticizer content of polymers, the glass transition temperature is reduced, which increases the free volume of the polymer and ultimately the diffusivity of the plasticizers ( Aziz et al., 2018; Joubert et al., 2002; Mauritz et al., 1990; Tsai and Chiu, 2022; Wei et al., 2019 ).
How does temperature affect the diffusion of plasticizers?
The diffusion of plasticizers from PVC to surrounding media increases with temperature. In polymers, diffusion is an activated process. As the temperature is increased, the diffusion coefficient increases, indicative of a positive activation energy for diffusion.
Is polyvinylchloride plasticized with a natural polymeric plasticizer?
da Silva MA, Vieira MGA, Maçumoto ACG, Beppu MM (2011) Polyvinylchloride (PVC) and natural rubber films plasticized with a natural polymeric plasticizer obtained through polyesterification of rice fatty acid. Polym Testing 30:478–484